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Dynamic Changes in Dimensional Structures of Co-Complex Crystals

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posted on 2010-10-18, 00:00 authored by Atsushi Kondo, Tomohiro Nakagawa, Hiroshi Kajiro, Ayako Chinen, Yoshiyuki Hattori, Fujio Okino, Tomonori Ohba, Katsumi Kaneko, Hirofumi Kanoh
A two-dimensional flexible porous coordination polymer (2D-PCP) that shows expansion/shrinkage structural transformation accompanied by molecular accommodation was synthesized by control of dimensionality in zero-dimensional and one-dimensional PCPs: The dynamic structural transformation cooperatively proceeds in the solid state with a drastic molecular rearrangement. Kinetics of the structural transformation was investigated.

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