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Dual Chiral, Dual Supramolecular Diastereodifferentiating Photocyclodimerization of 2-Anthracenecarboxylate Tethered to Amylose Scaffold
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posted on 2010-08-06, 00:00 authored by Gaku Fukuhara, Tomohiro Nakamura, Cheng Yang, Tadashi Mori, Yoshihisa InoueNewly synthesized 6-O-(2-anthroyl)amylose (AC-Am; 51% substitution) was photolyzed in (aqueous) DMSO solutions to give HH dimers as major products (after saponification), with modest enantiomeric excesses (ee) of 12−15% and 1−2% for syn-HT and anti-HH dimers, respectively. Addition of γ-cyclodextrin switched the product selectivity to HT and enhanced the ee of syn-HT up to 37%, while the chiral sense of anti-HH was inverted by changing the irradiation temperature, demonstrating usefulness of the dual-supramolecular approach to photochirogenesis.
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eeenantiomeric excessesTetheredchiral senseirradiation temperaturesaponificationAmylose ScaffoldphotochirogenesiapproachcyclodextrinAnthracenecarboxylateproduct selectivityHTsubstitutionDual Supramolecular Diastereodifferentiating PhotocyclodimerizationHH dimersphotolyzedDual ChiralDMSO solutionsusefulness
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