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Diamination of Conjugated Dienes and Trienes Catalyzed by N-Heterocyclic Carbene−Pd(0) Complexes

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journal contribution
posted on 31.08.2007 by Liang Xu, Haifeng Du, Yian Shi
This paper describes a diamination process using di-t-butyldiaziridinone as nitrogen source and N-heterocyclic carbene−Pd(0) complex as catalyst. A wide variety of conjugated dienes and trienes can be effectively diaminated in good yields with high regio- and stereoselectivities.