ie503798k_si_001.pdf (1.15 MB)
Development of a Semicontinuous Spray Process for the Production of Superhydrophobic Coatings from Supercritical Carbon Dioxide Solutions
journal contribution
posted on 2015-01-28, 00:00 authored by Pontus Olin, Caroline Hyll, Louise Ovaskainen, Marcus Ruda, Oskar Schmidt, Charlotta Turner, Lars WågbergSuperhydrophobic surfaces have been
fabricated in a continuous
spray process, where an alkyl ketene dimer (AKD) wax is dissolved
in supercritical carbon dioxide (scCO2) and sprayed onto
the substrate. The mass of extracted AKD from scCO2 has
been investigated as well as the pressure, temperature, and flow of
CO2 at the steady-state spray conditions. Several different
substrates such as glass, aluminum, paper, poly(ethylene terephthalate)
(PET), and polytetrafluoroethylene (PTFE) have been successfully coated,
and the superhydrophobic properties have been evaluated by measurement
of water contact angle, water drop friction, scanning electron microscopy
(SEM), and surface topography. The most efficient spray process, considering
surface properties and mass of extracted AKD, is obtained at the lowest
temperature investigated, 67 °C, and the highest pressure evaluated
in this study, 25 MPa. We also show that the influence of preexpansion
conditions (p, T) on the surface
temperature at the selected spray distance (3 cm) is negligible by
measurement with an infrared camera during spraying.