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Designed Construction of Cluster Organic Frameworks from Lindqvist-type Polyoxovanadate Cluster

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posted on 2018-08-09, 20:29 authored by Xin-Xiong Li, Lin-Jie Zhang, Cai-Yan Cui, Rui-Hu Wang, Guo-Yu Yang
Two unprecedented examples of cluster organic frameworks (TBA)3Cu­[V6O13(L)2]2·4DEF (2) (TBA)­Ag­[V6O13(L)2] solvent (3) (TBA = tetrabutylammonium, H3L = tris­(hydroxymethyl)-4-picoline, DEF = N,N′-diethylformamide) based on Lindqvist-type polyoxometalate (POM) secondary building units (SBUs) have been constructed successfully. Compounds 2 and 3 are the second cases of cluster organic frameworks based on Lindqvist-type POM cluster SBUs. Furthermore, the cluster organic framework of 2 exhibits efficient electrocatalytic activity and strong durability in oxygen reduction reaction.

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