ic8b01528_si_001.pdf (579.06 kB)
Designed Construction of Cluster Organic Frameworks from Lindqvist-type Polyoxovanadate Cluster
journal contribution
posted on 2018-08-09, 20:29 authored by Xin-Xiong Li, Lin-Jie Zhang, Cai-Yan Cui, Rui-Hu Wang, Guo-Yu YangTwo unprecedented
examples of cluster organic frameworks (TBA)3Cu[V6O13(L)2]2·4DEF (2) (TBA)Ag[V6O13(L)2] solvent (3) (TBA = tetrabutylammonium, H3L = tris(hydroxymethyl)-4-picoline,
DEF = N,N′-diethylformamide)
based on Lindqvist-type polyoxometalate (POM) secondary building units
(SBUs) have been constructed successfully. Compounds 2 and 3 are the second cases of cluster organic frameworks
based on Lindqvist-type POM cluster SBUs. Furthermore, the cluster
organic framework of 2 exhibits efficient electrocatalytic
activity and strong durability in oxygen reduction reaction.