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Density-Functional Theory Calculations of Aqueous Redox Potentials of Fourth-Period Transition Metals
journal contribution
posted on 2003-11-20, 00:00 authored by Merle Uudsemaa, Toomas TammAqueous M3+/M2+ redox potentials for nine of the ten fourth-period transition metals, M, have been calculated
with the use of DFT methodology in combination with the COSMO continuum model. Entropy contributions
to the potentials are taken from experiments. The model introduces no adjustable parameters beyond those
present in the underlying theoretical models. Inclusion of two solvation spheres (18 water molecules) is
necessary. For the ions studied, the average absolute difference from experimental values is 0.29 V, with
four out of nine potentials (those of V, Cr, Fe, Cu) reproduced with better than 0.1 V accuracy.