ol8b00851_si_001.pdf (10.01 MB)
Chiral Phthalocyanines through Axial Coordination
journal contribution
posted on 2018-04-20, 16:49 authored by Dora M. Răsădean, Tiberiu M. Gianga, Alexander H. Swan, Gabriele Kociok-Köhn, G. Dan PantoşA novel
approach to axially induce chirality on silicon phthalocyanines
via a microwave-assisted route is reported. CD analysis provides spectroscopic
evidence that chirality is transferred onto both Soret and Q-bands
of the phthalocyanine core. A chiral naphthalenediimide ligand was
found to induce the largest Cotton effect on the macrocycle absorptions.