ic901437e_si_002.cif (39.16 kB)
Catalytic Water Oxidation by Single-Site Ruthenium Catalysts
dataset
posted on 2010-02-15, 00:00 authored by Javier J. Concepcion, Jonah W. Jurss, Michael R. Norris, Zuofeng Chen, Joseph L. Templeton, Thomas J. MeyerA series of monomeric ruthenium polypyridyl complexes have been synthesized and characterized, and their performance as water oxidation catalysts has been evaluated. The diversity of ligand environments and how they influence rates and reaction thermodynamics create a platform for catalyst design with controllable reactivity based on ligand variations.