C–H Bonds Phosphorylation of Ketene Dithioacetals

Zhu, Liping; Yu, Hongmei; Guo, Quanping; Chen, Qiao; Xu, Zhaoqing; Wang, Rui

doi:10.1021/acs.orglett.5b00728.s001

C–H Bonds Phosphorylation of Ketene Dithioacetals

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posted on 2015-04-17, 00:00 authored by Liping Zhu, Hongmei Yu, Quanping Guo, Qiao Chen, Zhaoqing Xu, Rui Wang

C–H bond phosphorylation of ketene dithioacetals was achieved under transition-metal-free or AgNO₃ mediated conditions. Synthetic transformations of the coupling product provided promising methods for the construction of highly functionalized phosphorylated N-heterocycles and tetrasubstituted alkenes.

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functionalized DithioacetalsC ketene dithioacetals tetrasubstituted alkenes Phosphorylation construction Bond AgNO 3 phosphorylated phosphorylation method Synthetic transformations Ketene bond

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C–H Bonds Phosphorylation of Ketene Dithioacetals

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