cg300099m_si_002.cif (215.15 kB)
Anion-Assisted Formation of Discrete Homodimeric and Heterotetrameric Assemblies by Benzene Based Protonated Heteroaryl Receptors
dataset
posted on 2012-04-04, 00:00 authored by M. Arunachalam, Sourav Chakraborty, S. Marivel, Pradyut GhoshAnion-assisted formation of discrete homodimeric and
heterotetrameric
assemblies by benzene based protonated heteroaryl receptors L1–L6 have been studied thoroughly by single crystal X-ray
diffraction studies. Crystallographic results elucidate the fact that
protonated tripodal receptor L1 formed staggered homodimeric capsular assemblies 2 and 3 with CF3COO– and ClO4– ions, respectively. Protonation of L3 with trimesic acid also showed the formation
homodimeric assembly, 6. In all these cases the anions
are hydrogen bonded to the receptor molecules and show remarkable
influence on the outcome of the self-assembly process to form discrete
capsules. The necessity of the alkyl substitution on the benzene platform
has been established from complexes 8, 9, and 10, which were obtained upon protonation of L6 with HNO3, HI, and HClO4, respectively. Interestingly, when a 1:1 mixture of L1 (tripodal) and L5 (dipodal) were treated with HClO4 and HBF4, discrete heterotetrameric assemblies have been
isolated as complexes 11 and 12. The detailed
solid state structural analysis of these complexes revealed the formation
of heterotetrameric assemblies assisted by anion–water clusters.
Correlation of these solid state structural assemblies with our previously
reported complexes 1, 4, 5,
and 7 has also been described. The role of anionic templates
in assisting the formation of discrete capsular assemblies from receptors
possessing heteroaryl units and 1,3,5-methyl substituted benzene platform
has been established.