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An Efficient Oxidative Lactonization of 1,4-Diols Catalyzed by Cp*Ru(PN) Complexes
journal contribution
posted on 2007-04-26, 00:00 authored by Masato Ito, Akihide Osaku, Akira Shiibashi, Takao IkariyaAn efficient oxidative lactonization of 1,4-diols in acetone is accomplished by the well-defined ruthenium catalyst, whose bifunctional nature
underlies the high efficiency as well as unique chemo- and regioselectivity of the reaction which provides a rapid access to γ-butyrolactones
including flavor lactones hinokinin, and muricatacin.