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An Efficient Cost-Effective Removal of Ca2+, Mg2+, and Cu2+ Ions from Aqueous Medium Using Chlorosodalite Synthesized from Coal Fly Ash
journal contribution
posted on 2017-01-17, 15:33 authored by Ashok V. Borhade, Sanjay R. KankrejFly
ash is one of the coal combustion solid wastes which causes
environmental problems around the world. In this context for the first
time, this paper reports the conversion of coal fly ash (CFA) into
aluminosilicate chlorosodalite, Na8[AlSiO4]6Cl2. The synthesized chlorosodalite was analyzed
by X-ray diffraction, Fourier transform infrared, scanning electron
microscopy, and Brunauer–Emmett–Teller surface area
measurements. The synthesized aluminosilicate chlorosodalite material
was tested for potential applications for the removal of calcium,
magnesium, and copper from their aqueous medium. The catch method
was successfully used to study the effect of the initial concentration
of metal ions, adsorbent dose, and contact time. The equilibrium data
obtained were fitted by the Langmuir, Freundlich, Temkin, and Dubinin–Radushkevich
isotherm models and showed the affinity order Cu2+ >
Ca2+ > Mg2+. The well-known thermodynamic
aspects
such as the variation in Gibbs free energy (ΔG), entropy (ΔS), and enthalpy (ΔH) were also evaluated. Further the kinetic parameters including
the rate constant and the order of sorption process were also determined.
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Keywords
coal combustionpaper reportsequilibrium dataadsorbent dosemetal ionsAqueous Mediumscanning electron microscopyEfficient Cost-Effective RemovalChlorosodalite SynthesizedX-ray diffractionMgsorption processaluminosilicate chlorosodalite material6 Cl 2contact timeAlSiO 4aluminosilicate chlorosodaliteCuNa 8CFA
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