A “Strongly”
Self-Catenated Metal–Organic Framework with the Highest Topological
Density among 3,4-Coordinated Nets

Ma, Huiqing; Sun, Di; Zhang, Liangliang; Wang, Rongming; Blatov, Vladislav A.; Guo, Jie; Sun, Daofeng

doi:10.1021/ic4018757.s002

ic4018757_si_002.pdf (533.47 kB)

A “Strongly” Self-Catenated Metal–Organic Framework with the Highest Topological Density among 3,4-Coordinated Nets

journal contribution

posted on 2013-10-07, 00:00 authored by Huiqing Ma, Di Sun, Liangliang Zhang, Rongming Wang, Vladislav A. Blatov, Jie Guo, Daofeng Sun

A new type of 3D “strongly” self-catenated metal–organic framework (SDU-9) has been constructed from [Cu₂(COO)₄] paddlewheel secondary building units and a tripodal carboxylate linker. SDU-9 ([Cu₆(H₂O)₆L₄]·24H₂O, where [H₃L = 4,4′,4″-(hydroxysilanetriyl)tris(triphenyl-4-carboxylic acid), represents a rare example of a highly symmetrical coordination network and extremely tight self-catenation. To the best of our knowledge, SDU-9 has the highest topological density among all known 3,4-coordinated nets.