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A Mixed-Cluster Approach for Building a Highly Porous Cobalt(II) Isonicotinic Acid Framework: Gas Sorption Properties and Computational Analyses

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posted on 2017-02-20, 12:50 authored by Di-Ming Chen, Nan-Nan Zhang, Chun-Sen Liu, Zhi-Hao Jiang, Xing-Dong Wang, Miao Du
A unique channel-type metal–organic framework (MOF) built up from mixed square-planar Co42-OH)44-OH) and cuboidal Co43-OH)4 clusters with an isonicotinic acid ligand has been successfully fabricated that demonstrates the highest specific surface area and high H2 uptake capacities among all of the cobalt­(II) isonicotinic acid frameworks reported so far.

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