cg500235j_si_002.cif (20.28 kB)
A Microporous Metal–Organic Framework Constructed from a New Tetracarboxylic Acid for Selective Gas Separation
dataset
posted on 2014-05-07, 00:00 authored by Hussah Alawisi, Bin Li, Yabing He, Hadi D. Arman, Abdullah
M. Asiri, Hailong Wang, Banglin ChenA new
organic ligand of pyrene-containing tetracarboxylic acid
and its first metal–organic framework UTSA-72 was
designed and synthesized. The MOF has the two-dimensional (4,4) framework
topology. The activated UTSA-72a exhibits permanent porosity
and moderately high selectivities for CO2/N2, C2H2/CH4, and CO2/CH4 gas separations at room temperature because of the small
pores within the framework.
