Enantioselective total syntheses of (−)-clavaminol A and deacetyl (+)-clavaminol H Rachana Pandey Anju Gehlawat Ranjana Prakash Satyendra Kumar Pandey 10.6084/m9.figshare.6955058.v1 https://tandf.figshare.com/articles/journal_contribution/Enantioselective_total_syntheses_of_-clavaminol_A_and_deacetyl_-clavaminol_H/6955058 <p>An efficient enantioselective approach to the syntheses of (−)-clavaminol A and deacetyl (+)-clavaminol H is presented, starting from <i>n</i>-decanol. The synthesis features Sharpless asymmetric dihydroxylation (AD), regioselective epoxide formation/opening and <i>α</i>-tosylation as key steps.</p> 2018-08-10 13:34:57 2-amino-3-alkanols clavaminols cytotoxic Sharpless AD regioselective