Yang, Xiao-Hui Davison, Ryan T. Dong, Vy M. Catalytic Hydrothiolation: Regio- and Enantioselective Coupling of Thiols and Dienes We report a Rh-catalyzed hydrothiolation of 1,3-dienes, including petroleum feedstocks. Either secondary or tertiary allylic sulfides can be generated from the selective addition of a thiol to the more substituted double bond of a diene. The catalyst tolerates a wide range of functional groups, and the loading can be as low as 0.1 mol %. Enantioselective;0.1;diene;allylic sulfides;Thiol;loading;Regio;Catalytic Hydrothiolation;catalyst;mol;petroleum feedstocks;Diene;Rh-catalyzed hydrothiolation;bond 2018-08-09
    https://acs.figshare.com/articles/journal_contribution/Catalytic_Hydrothiolation_Regio-_and_Enantioselective_Coupling_of_Thiols_and_Dienes/6953030
10.1021/jacs.8b06957.s001