Heterometallic mixed-valence complex with a {Co<sup>II</sup>Co<sup>III</sup>Cu<sub>2</sub>O<sub>4</sub>} core as a new type of cobalt-based oxide cubane
Oleh Stetsiuk
Abdelkrim El-Ghayoury
Vladimir N. Kokozay
Narcis Avarvari
Svitlana R. Petrusenko
10.6084/m9.figshare.5816625.v1
https://tandf.figshare.com/articles/journal_contribution/Heterometallic_mixed-valence_complex_with_a_Co_sup_II_sup_Co_sup_III_sup_Cu_sub_2_sub_O_sub_4_sub_core_as_a_new_type_of_cobalt-based_oxide_cubane/5816625
<p>A tetranuclear heterometallic complex formulated as [Co<sub>2</sub>Cu<sub>2</sub>(L)<sub>3</sub>(ea)(H<sub>2</sub>O)(NCS)<sub>2</sub>], where H<sub>2</sub>L = 2-((2-hydroxyethyl)iminomethyl)-phenol and Hea = 2-aminoethanol, has been obtained by self-assembly and characterized by single crystal X-ray diffraction. The crystal structure of the complex represents a new {Co<sup>II</sup>Co<sup>III</sup>M<sub>2</sub>} type of cobalt-based oxide cubane complex according to the classification which has been made via CSD structural analysis.</p>
2018-01-24 06:15:52
Heterometallic complex
Schiff base ligand
cubane complex
copper
cobalt