Heterometallic mixed-valence complex with a {Co<sup>II</sup>Co<sup>III</sup>Cu<sub>2</sub>O<sub>4</sub>} core as a new type of cobalt-based oxide cubane Oleh Stetsiuk Abdelkrim El-Ghayoury Vladimir N. Kokozay Narcis Avarvari Svitlana R. Petrusenko 10.6084/m9.figshare.5816625.v1 https://tandf.figshare.com/articles/journal_contribution/Heterometallic_mixed-valence_complex_with_a_Co_sup_II_sup_Co_sup_III_sup_Cu_sub_2_sub_O_sub_4_sub_core_as_a_new_type_of_cobalt-based_oxide_cubane/5816625 <p>A tetranuclear heterometallic complex formulated as [Co<sub>2</sub>Cu<sub>2</sub>(L)<sub>3</sub>(ea)(H<sub>2</sub>O)(NCS)<sub>2</sub>], where H<sub>2</sub>L = 2-((2-hydroxyethyl)iminomethyl)-phenol and Hea = 2-aminoethanol, has been obtained by self-assembly and characterized by single crystal X-ray diffraction. The crystal structure of the complex represents a new {Co<sup>II</sup>Co<sup>III</sup>M<sub>2</sub>} type of cobalt-based oxide cubane complex according to the classification which has been made via CSD structural analysis.</p> 2018-01-24 06:15:52 Heterometallic complex Schiff base ligand cubane complex copper cobalt