10.1021/acs.orglett.7b03901.s001
Dong Hyuk Kim
Dong
Hyuk Kim
Juyoung Lee
Juyoung
Lee
Anna Lee
Anna
Lee
Visible-Light-Driven Silver-Catalyzed One-Pot Approach:
A Selective Synthesis of Diaryl Sulfoxides and Diaryl Sulfones
American Chemical Society
2018
reaction conditions
photocatalyst
aryl thiols
aryl diazonium salts
air atmosphere
diaryl sulfoxides
absence
Visible-Light-Driven Silver-Catalyzed One-Pot Approach
synthesis
diaryl sulfones
Diaryl Sulfoxides
singlet-oxygen-induced oxidation
one-pot approach
room temperature
visible-light-driven silver catalysis
Selective Synthesis
Diaryl Sulfones
2018-01-18 17:18:39
Journal contribution
https://acs.figshare.com/articles/journal_contribution/Visible-Light-Driven_Silver-Catalyzed_One-Pot_Approach_A_Selective_Synthesis_of_Diaryl_Sulfoxides_and_Diaryl_Sulfones/5799225
An efficient one-pot
approach for the synthesis of diaryl sulfoxides
and diaryl sulfones using aryl thiols and aryl diazonium salts was
developed. The use of a visible-light-driven silver catalysis and
the subsequent singlet-oxygen-induced oxidation enabled selective
synthesis of sulfoxides and sulfones in the absence of a photocatalyst.
The reactions were carried out under mild reaction conditions; the
desired products were obtained under air atmosphere at room temperature.