%0 Generic
%A Jiang, Sheng-Peng
%A Zhang, Mengmeng
%A Wang, Cheng-Yu
%A Yang, Shangfeng
%A Wang, Guan-Wu
%D 2017
%T Cascade Radical Reaction of N‑Sulfonyl-2-allylanilines
with [60]Fullerene: Synthesis and Functionalization of (2-Indolinyl)methylated
Hydrofullerenes
%U https://acs.figshare.com/articles/dataset/Cascade_Radical_Reaction_of_i_N_i_Sulfonyl-2-allylanilines_with_60_Fullerene_Synthesis_and_Functionalization_of_2-Indolinyl_methylated_Hydrofullerenes/5406757
%R 10.1021/acs.orglett.7b02343.s002
%2 https://ndownloader.figshare.com/files/9320794
%K photovoltaic devices
%K fullerene
%K Functionalization
%K copper-promoted cascade
%K Hydrofullerene
%K substrate scope
%K basis
%K sulfonyl -2-allylanilines
%K application
%K Fullerene
%K transformation
%K Synthesi
%K hydrofullerene
%K group tolerance
%K formation
%K Indolinyl
%K reaction mechanism
%K indolinyl
%K Sulfonyl
%K cascade Radical Reaction
%K carbocyclic derivatives
%X The copper-promoted
cascade radical reaction of N-sulfonyl-2-allylanilines
with [60]fullerene has been developed to
efficiently provide novel and scarce (2-indolinyl)methylated hydrofullerenes,
featuring a broad substrate scope and excellent functional group tolerance.
A plausible reaction mechanism for the formation of (2-indolinyl)methylated
hydrofullerenes is proposed on the basis of the experimental results.
In addition, further transformation into other carbocyclic derivatives
of [60]fullerene as well as their applications in organic photovoltaic
devices of the obtained products has also been explored.
%I ACS Publications