%0 Generic %A Jiang, Sheng-Peng %A Zhang, Mengmeng %A Wang, Cheng-Yu %A Yang, Shangfeng %A Wang, Guan-Wu %D 2017 %T Cascade Radical Reaction of N‑Sulfonyl-2-allylanilines with [60]Fullerene: Synthesis and Functionalization of (2-Indolinyl)­methylated Hydrofullerenes %U https://acs.figshare.com/articles/dataset/Cascade_Radical_Reaction_of_i_N_i_Sulfonyl-2-allylanilines_with_60_Fullerene_Synthesis_and_Functionalization_of_2-Indolinyl_methylated_Hydrofullerenes/5406757 %R 10.1021/acs.orglett.7b02343.s002 %2 https://ndownloader.figshare.com/files/9320794 %K photovoltaic devices %K fullerene %K Functionalization %K copper-promoted cascade %K Hydrofullerene %K substrate scope %K basis %K sulfonyl -2-allylanilines %K application %K Fullerene %K transformation %K Synthesi %K hydrofullerene %K group tolerance %K formation %K Indolinyl %K reaction mechanism %K indolinyl %K Sulfonyl %K cascade Radical Reaction %K carbocyclic derivatives %X The copper-promoted cascade radical reaction of N-sulfonyl-2-allylanilines with [60]­fullerene has been developed to efficiently provide novel and scarce (2-indolinyl)­methylated hydrofullerenes, featuring a broad substrate scope and excellent functional group tolerance. A plausible reaction mechanism for the formation of (2-indolinyl)­methylated hydrofullerenes is proposed on the basis of the experimental results. In addition, further transformation into other carbocyclic derivatives of [60]­fullerene as well as their applications in organic photovoltaic devices of the obtained products has also been explored. %I ACS Publications