10.1021/acs.orglett.7b02343.s002
Sheng-Peng Jiang
Sheng-Peng
Jiang
Mengmeng Zhang
Mengmeng
Zhang
Cheng-Yu Wang
Cheng-Yu
Wang
Shangfeng Yang
Shangfeng
Yang
Guan-Wu Wang
Guan-Wu
Wang
Cascade Radical Reaction of <i>N</i>‑Sulfonyl-2-allylanilines
with [60]Fullerene: Synthesis and Functionalization of (2-Indolinyl)methylated
Hydrofullerenes
American Chemical Society
2017
photovoltaic devices
fullerene
Functionalization
copper-promoted cascade
Hydrofullerene
substrate scope
basis
sulfonyl -2-allylanilines
application
Fullerene
transformation
Synthesi
hydrofullerene
group tolerance
formation
Indolinyl
reaction mechanism
indolinyl
Sulfonyl
cascade Radical Reaction
carbocyclic derivatives
2017-09-14 15:18:59
Dataset
https://acs.figshare.com/articles/dataset/Cascade_Radical_Reaction_of_i_N_i_Sulfonyl-2-allylanilines_with_60_Fullerene_Synthesis_and_Functionalization_of_2-Indolinyl_methylated_Hydrofullerenes/5406757
The copper-promoted
cascade radical reaction of <i>N</i>-sulfonyl-2-allylanilines
with [60]fullerene has been developed to
efficiently provide novel and scarce (2-indolinyl)methylated hydrofullerenes,
featuring a broad substrate scope and excellent functional group tolerance.
A plausible reaction mechanism for the formation of (2-indolinyl)methylated
hydrofullerenes is proposed on the basis of the experimental results.
In addition, further transformation into other carbocyclic derivatives
of [60]fullerene as well as their applications in organic photovoltaic
devices of the obtained products has also been explored.