10.1021/acs.orglett.7b02343.s002 Sheng-Peng Jiang Sheng-Peng Jiang Mengmeng Zhang Mengmeng Zhang Cheng-Yu Wang Cheng-Yu Wang Shangfeng Yang Shangfeng Yang Guan-Wu Wang Guan-Wu Wang Cascade Radical Reaction of <i>N</i>‑Sulfonyl-2-allylanilines with [60]Fullerene: Synthesis and Functionalization of (2-Indolinyl)­methylated Hydrofullerenes American Chemical Society 2017 photovoltaic devices fullerene Functionalization copper-promoted cascade Hydrofullerene substrate scope basis sulfonyl -2-allylanilines application Fullerene transformation Synthesi hydrofullerene group tolerance formation Indolinyl reaction mechanism indolinyl Sulfonyl cascade Radical Reaction carbocyclic derivatives 2017-09-14 15:18:59 Dataset https://acs.figshare.com/articles/dataset/Cascade_Radical_Reaction_of_i_N_i_Sulfonyl-2-allylanilines_with_60_Fullerene_Synthesis_and_Functionalization_of_2-Indolinyl_methylated_Hydrofullerenes/5406757 The copper-promoted cascade radical reaction of <i>N</i>-sulfonyl-2-allylanilines with [60]­fullerene has been developed to efficiently provide novel and scarce (2-indolinyl)­methylated hydrofullerenes, featuring a broad substrate scope and excellent functional group tolerance. A plausible reaction mechanism for the formation of (2-indolinyl)­methylated hydrofullerenes is proposed on the basis of the experimental results. In addition, further transformation into other carbocyclic derivatives of [60]­fullerene as well as their applications in organic photovoltaic devices of the obtained products has also been explored.