Al-Huniti, Mohammed H. Sullivan, Zachary B. Stanley, Jarrod L. A. Carson, James F. Dempsey Hyatt, I. Hairston, A. Christina Croatt, Mitchell P. Hypervalent Iodonium Alkynyl Triflate Generated Phenylcyanocarbene and Its Reactivity with Aromatic Systems Phenylcyanocarbene was generated by the reaction of azide with a hypervalent iodonium alkynyl triflate and reacted <i>in situ</i> with 21 different carbocyclic and heterocyclic aromatic compounds. These reactions led to more complex products that frequently underwent subsequent rearrangements. The reactivity was further explored in a mechanistic study to ascertain the chemoselectivity and stereospecificity. Reactivity;chemoselectivity;carbocyclic;hypervalent iodonium alkynyl triflate;azide;reactivity;stereospecificity;compound;Hypervalent Iodonium Alkynyl Triflate Generated Phenylcyanocarbene;Aromatic Systems Phenylcyanocarbene;heterocyclic;rearrangement 2017-08-25
    https://acs.figshare.com/articles/dataset/Hypervalent_Iodonium_Alkynyl_Triflate_Generated_Phenylcyanocarbene_and_Its_Reactivity_with_Aromatic_Systems/5382490
10.1021/acs.joc.7b01608.s003