TY - DATA T1 - Synthesis and X−ray structures of thioxo− and selenoxo−phosphino species derived from monooxidation of new N-(4-acetylphenyl)-P, P-diphenylphosphinous amide ligand PY - 2017/11/28 AU - Harbi Tomah Al-Masri AU - Ziad Moussa UR - https://tandf.figshare.com/articles/dataset/Synthesis_and_X_ray_structures_of_thioxo_and_selenoxo_phosphino_species_derived_from_monooxidation_of_new_i_N_i_-_4-acetylphenyl_-_i_P_P_i_-diphenylphosphinous_amide_ligand/5378341 DO - 10.6084/m9.figshare.5378341.v2 L4 - https://ndownloader.figshare.com/files/9827872 L4 - https://ndownloader.figshare.com/files/9251182 KW - Chlorodiphenylphosphine KW - monoselenide KW - monosulfide KW - phosphine KW - P−N ligand N2 - The reaction of p-acetylaniline with chlorodiphenylphosphine afforded the new ligand (p-CH3CO)C6H4N(H)PPh2 (1) in good yield. Monooxidized thioxo (p-CH3CO)C6H4N(H)P(S)Ph2 (2) and selenoxo (p-CH3CO)C6H4N(H)P(Se)Ph2 (3) were synthesized by the reaction of 1 with elemental sulfur or grey selenium. Compounds 1–3 were identified and characterized by multinuclear NMR spectroscopy (1H, 13C, 31P, 77Se NMR) and elemental analysis. Compounds 2 and 3 were structurally characterized by single crystal X-ray diffraction which showed that the p-acetyl substituent on the aniline aromatic ring has a profound influence on the elongation of the P−N bond distance compared to several structurally characterized analogues found in literature. As such, subsequent reactions involving the P-N bond (i.e. insertion reactions) may be influenced in a favorable manner and proceed with ease. ER -