%0 Journal Article %A Zhou, Weijie %A Gu, Meng %A Ou, Yiyi %A Zhang, Caihua %A Zhang, Xuejie %A Zhou, Lei %A Liang, Hongbin %D 2017 %T Concentration-Driven Selectivity of Energy Transfer Channels and Color Tunability in Ba3La(PO4)3:Tb3+, Sm3+ for Warm White LEDs %U https://acs.figshare.com/articles/journal_contribution/Concentration-Driven_Selectivity_of_Energy_Transfer_Channels_and_Color_Tunability_in_Ba_sub_3_sub_La_PO_sub_4_sub_sub_3_sub_Tb_sup_3_sup_Sm_sup_3_sup_for_Warm_White_LEDs/5116210 %R 10.1021/acs.inorgchem.7b00737.s001 %2 https://ndownloader.figshare.com/files/8687524 %K CCT %K emission color %K chromaticity stability %K interaction mechanisms %K near-UV WLED %K concentration-dependent 5 D 3 %K ET processes %K 5 D 3 %K 5 D 4 channel %K 5 D 4 emissions %K concentration-driven selectivity %K 5 D 3 channel %K 5 D 4 channels %K light-emitting diodes %K PO 4 %K Warm White LEDs %K Energy Transfer Channels %K Concentration-Driven Selectivity %K emission color tunability %K Sm %K phosphor %K Tb %K BLPO %K Color Tunability %K doping concentrations %K energy transfer %X Here, we report the large-scale emission color tunability in Ba3La­(PO4)3:Tb3+, Sm3+ (BLPO:TS) system based on the detailed discussion on the concentration-driven selectivity of energy transfer (ET) channels from Tb3+ to Sm3+. It is induced by the concentration-dependent 5D3 and 5D4 emissions of Tb3+ and the different interaction mechanisms of ET from Tb3+ to Sm3+ via 5D3 and 5D4 channels. In the diluted Tb3+ scenario, the red emission of Sm3+ is efficiently sensitized via the 5D3 channel, while in the concentrated Tb3+ case, the contribution of 5D4 channel is dominant. Therefore, by simply adjusting the doping concentrations of Tb3+ and Sm3+, the emission color of the phosphors can be tuned from green to red. In view of the phosphors with red emissions are critical to the warm white light-emitting diodes (WLEDs), an orange-red Tb3+, Sm3+ coactivated phosphor Ba3La0.90Tb0.05Sm0.05(PO4)3 (BLPO:5T5S) with good thermal and chromaticity stability and internal quantum efficiency ∼67% is developed in the system. Then, a near-UV WLED (CCT ≈ 4500 K, Ra ≈ 81) is fabricated using this phosphor. These findings not only indicate that the orange-red phosphor BLPO:5T5S is available for near-UV warm white LEDs but also deliver new insights into the ET processes in Tb3+ and Sm3+ activated phosphors. %I ACS Publications