TY - DATA T1 - New red-luminescent cadmium coordination polymers with 4-amino-2,1,3-benzothiadiazole PY - 2016/09/02 AU - T. S. Sukhikh AU - D. S. Ogienko AU - D. A. Bashirov AU - N. V. Kuratieva AU - V. YU. Komarov AU - M. I. Rakhmanova AU - S. N. Konchenko UR - https://tandf.figshare.com/articles/journal_contribution/New_red-luminescent_cadmium_coordination_polymers_with_4-amino-2_1_3-benzothiadiazole/3804144 DO - 10.6084/m9.figshare.3804144.v1 L4 - https://ndownloader.figshare.com/files/5922981 KW - Benzothiadiazole KW - polymer KW - cadmium KW - photoluminescence KW - red emission N2 - New polymeric cadmium complexes, α-[CdLCl2]n (1), [CdL2Cl2]n (2) and β-[CdLCl2]n (3) (L = 4-amino-2,1,3-benzothiadiazole), were obtained as products of the reaction of CdCl2 with L. The synthetic procedures allowing isolation of pure 1–3 were optimized. The structures of 1–3 were established by single-crystal X-ray diffraction and the compounds were characterized by UV–Vis and IR spectroscopy. In these compounds, L is either μ-bridging (1) or terminal (2 and 3). The UV–Vis spectra of the complexes in the solid state resemble that of free L. However, coordination of L leads to a significant shift of emission in photoluminescence spectra from yellow (free L) to red (1–3). ER -