TY - DATA T1 - Formation of Ethylene-Bridged Dinuclear IrIII Species via M−C Coupling of IrII and IrII(ethene) PY - 2002/09/20 AU - Bas de Bruin AU - Simone Thewissen AU - Tsi-Wai Yuen AU - Theo P. J. Peters AU - Jan M. M. Smits AU - Anton W. Gal UR - https://acs.figshare.com/articles/journal_contribution/Formation_of_Ethylene-Bridged_Dinuclear_Ir_sup_III_sup_Species_via_M_C_Coupling_of_Ir_sup_II_sup_and_Ir_sup_II_sup_ethene_/3773295 DO - 10.1021/om020476m.s002 L4 - https://ndownloader.figshare.com/files/5882076 KW - Ir II KW - III KW - tpa KW - ethene N2 - Ethene dissociation from [(Mentpa)IrII(ethene)]2+, induced by coordination of acetonitrile, causes a rapid and selective M−C coupling between IrII and IrII(ethene), resulting in ethylene-bridged dinuclear iridium(III) complexes of the composition [{(Mentpa)IrIII(NCMe)}2(μ2-C2H4)]4+ (n = 2, 3). ER -