TY - DATA T1 - Remarkably High Asymmetric Amplification in the Chiral Lanthanide Complex-Catalyzed Hetero-Diels−Alder Reaction:  First Example of the Nonlinear Effect in ML3 System PY - 1999/12/14 AU - Hiroshi Furuno AU - Takeshi Hanamoto AU - Yuichi Sugimoto AU - Junji Inanaga UR - https://acs.figshare.com/articles/journal_contribution/Remarkably_High_Asymmetric_Amplification_in_the_Chiral_Lanthanide_Complex-Catalyzed_Hetero-Diels_Alder_Reaction_First_Example_of_the_Nonlinear_Effect_in_ML_sub_3_sub_System/3761355 DO - 10.1021/ol991189q.s001 L4 - https://ndownloader.figshare.com/files/5868648 KW - homochiral ML 3 complexes KW - ML 3 System KW - Remarkably High Asymmetric Amplification KW - radii KW - Lanthanide KW - amplification KW - Yb KW - mechanism KW - Chiral KW - BNP KW - Nonlinear Effect KW - ytterbium ion KW - catalyst KW - First KW - ligand KW - enantiopure KW - lanthanide metal ions KW - autogenetic formation N2 - A remarkably high asymmetric amplification was realized in the Yb[(R)-BNP]3-catalyzed hetero-Diels−Alder reaction as the first example in the metal/chiral ligand 1:3 system. The mechanism may be explained by the autogenetic formation of the enantiopure complex as the most active catalyst. The enantiomer-discriminative formation of homochiral ML3 complexes is quite general within the lanthanide metal ions with similar ionic radii to that of the ytterbium ion. ER -