Iodomethane Oxidation by
Dimethyldioxirane: A New Route to
Hypoiodous Acid and Iodohydrines
Gregorio Asensio
Cecilia Andreu
Carmen Boix-Bernardini
Rossella Mello
María Elena González-Nuñez
10.1021/ol9903281.s001
https://acs.figshare.com/articles/journal_contribution/Iodomethane_Oxidation_by_Dimethyldioxirane_A_New_Route_to_Hypoiodous_Acid_and_Iodohydrines/3759912
The oxidation of iodomethane with dimethyldioxirane allows the generation of stable neutral solutions of hypoiodous acid in the absence of
any trapping agent for iodide anion. Hypoiodous acid is trapped in situ by addition to representative olefins to give iodohydrines in good
yields. The stereochemical study of the products shows the <i>anti</i>-stereospecific nature of the iodohydroxylation reaction.
1999-12-03 00:00:00
iodomethane
hypoiodous acid
generation
Iodohydrine
agent
iodohydrine
absence
oxidation
stereospecific nature
iodohydroxylation reaction
Iodomethane Oxidation
Dimethyldioxirane
Hypoiodous acid
solution
yield
stereochemical study
New Route
representative olefins
dimethyldioxirane
iodide anion