10.1021/ol034958l.s001 Samir BouzBouz Samir BouzBouz Janine Cossy Janine Cossy Stereoselective Synthesis of the C1−C13 Fragment of (+)-Discodermolide Using Asymmetric Allyltitanations American Chemical Society 2003 Z configuration metathesi Stereoselective Synthesis Discodermolide Fragment aldehyde olefin discodermolide synthesis fragment Asymmetric Allyltitanations stereogenic centers crotyltitanation enantioselective allyl 2003-07-25 00:00:00 Journal contribution https://acs.figshare.com/articles/journal_contribution/Stereoselective_Synthesis_of_the_C1_C13_Fragment_of_-Discodermolide_Using_Asymmetric_Allyltitanations/3747591 The synthesis of the C1−C13 fragment of (+)-discodermolide has been achieved. The configurations of the stereogenic centers have been controlled by enantioselective allyl- and crotyltitanations of aldehydes, and the <i>Z</i> configuration of the olefin at C8−C9 was controlled by a ring-closing metathesis.