10.1021/ol015816z.s001
Peter Wipf
Peter
Wipf
Seth Ribe
Seth
Ribe
Water-Accelerated Tandem Claisen
Rearrangement−Catalytic Asymmetric
Carboalumination
American Chemical Society
2001
carboalumination
trialkylalane
oxidative
terminal alkenes
Asymmetric
Tandem
bond
tandem sequence
formation
Rearrangement
stoichiometric quantities
chiral
Carboalumination
Claisen reaction
quantity
2001-04-14 00:00:00
Journal contribution
https://acs.figshare.com/articles/journal_contribution/Water-Accelerated_Tandem_Claisen_Rearrangement_Catalytic_Asymmetric_Carboalumination/3739026
The addition of stoichiometric quantities of water accelerates both the trimethylaluminum-mediated aromatic Claisen reaction and the chiral
zirconocene-catalyzed asymmetric carboalumination of terminal alkenes. The two reactions occur in a tandem sequence resulting in the
selective formation of two new C−C and one C−O bond after oxidative quench of the intermediate trialkylalane.