%0 Journal Article
%A Jafarpour, Laleh
%A Nolan, Steven P.
%D 2000
%T Simply Assembled and Recyclable
Polymer-Supported Olefin Metathesis
Catalysts
%U https://acs.figshare.com/articles/journal_contribution/Simply_Assembled_and_Recyclable_Polymer-Supported_Olefin_Metathesis_Catalysts/3737556
%R 10.1021/ol0067134.s001
%2 https://ndownloader.figshare.com/files/5829324
%K Ru
%K bi
%K PCy 3
%K catalyst
%X Polymer-supported ruthenium catalysts (PCy3)2Ru(C(H)Ph)Cl2, (PCy3)Ru(IMes)(C(H)Ph)Cl2, and (PCy3)Ru(SIMes)(C(H)Ph)Cl2, where IMes
= 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene and SIMes = 1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene, have been prepared
and found to be effective “boomerang” catalysts for ring-closing metathesis. They are recyclable, show comparable or better reactivity than
their homogeneous counterparts, tolerate functional groups, and perform very well with dienes and moderately well with highly hindered
substrates.
%I ACS Publications