%0 Journal Article
%A Bazzicalupi, Carla
%A Bencini, Andrea
%A Berni, Emanuela
%A Bianchi, Antonio
%A Ciattini, Samuele
%A Giorgi, Claudia
%A Maoggi, Sauro
%A Paoletti, Piero
%A Valtancoli, Barbara
%D 2002
%T Synthesis of New Tren-Based
Tris-Macrocycles. Anion Cluster
Assembling Inside the Cavity Generated by
a Bowl-Shaped Receptor
%U https://acs.figshare.com/articles/journal_contribution/Synthesis_of_New_Tren-Based_Tris-Macrocycles_Anion_Cluster_Assembling_Inside_the_Cavity_Generated_by_a_Bowl-Shaped_Receptor/3693966
%R 10.1021/jo020474b.s002
%2 https://ndownloader.figshare.com/files/5784324
%K crystal structure
%K Na 6 Cl 2
%K polyammonium receptors
%K Anion Cluster Assembling
%K ClO 4
%K aneN
%K Cavity Generated
%K 12 compound
%K hydrogen bond interactions
%K tren unit
%K L 3
%X The synthesis of three new tris-macrocycles,
containing three [12]aneN4 (L1), [12]aneN3O (L2), or [14]aneN4 (L3) moieties appended to a tren unit, is reported.
The crystal structure of the [(Na(ClO4)6)⊂L12H13]Na6Cl2(ClO4)12 compound shows the anionic cluster [Na(ClO4)6]5-
assembled inside the cavity defined by two bowl-shaped
polyammonium receptors, held by multiple charge−charge
and hydrogen bond interactions.
%I ACS Publications