%0 Generic
%A Selby, Hugh D.
%A Orto, Peter
%A Carducci, Michael D.
%A Zheng, Zhiping
%D 2002
%T Novel Concentration-Driven Structural Interconversion in Shape-Specific
Solids Supported by the Octahedral [Re6(μ3-Se)8]2+ Cluster Core
%U https://acs.figshare.com/articles/dataset/Novel_Concentration-Driven_Structural_Interconversion_in_Shape-Specific_Solids_Supported_by_the_Octahedral_Re_sub_6_sub_sub_3_sub_-Se_sub_8_sub_sup_2_sup_Cluster_Core/3610014
%R 10.1021/ic025925p.s002
%2 https://ndownloader.figshare.com/files/5698527
%K Re
%K SbF
%K coordination
%K Cl
%K PPh 3
%K Se
%K dipyridyl
%X A complex containing the face-capped octahedral [Re6(μ3-Se)8]2+
cluster core, cis-[Re6(μ3-Se)8(PPh3)4(4,4‘-dipyridyl)2](SbF6)2 (1), is
used as a ditopic ligand with an enforced right angle between the
two 4,4‘-dipyridyl moieties for the coordination of Cd2+ ion. Two
coordination polymers, [{Re6(μ3-Se)8(PPh3)4(4,4‘-dipyridyl)2}2{Cd(NO3)2}](SbF6)4·21C4H10O·21CH2Cl2 (2) and [{Re6(μ3-Se)8(PPh3)4(4,4‘-dipyridyl)2}{Cd(NO3)3}](NO3)·2C4H10O·CH2Cl2 (3), are obtained. The relative concentration of Cd2+ determines which species
is isolated, and the conversion of the first structure into the second
is demonstrated experimentally.
%I ACS Publications