%0 Generic
%A Gong, Pifu
%A Jiang, Xingxing
%A Yang, Yi
%A Luo, Siyang
%A Huang, Rongjin
%A Li, Laifeng
%A Chen, Chuangtian
%A Lin, Zheshuai
%D 2016
%T Cs3W3PO13: A Tungsten
Phosphate with One-Dimensional Zigzag Tunnels Exhibiting Strongly
Anisotropic Thermal Expansion
%U https://acs.figshare.com/articles/dataset/Cs_sub_3_sub_W_sub_3_sub_PO_sub_13_sub_A_Tungsten_Phosphate_with_One_Dimensional_Zigzag_Tunnels_Exhibiting_Strongly_Anisotropic_Thermal_Expansion/3382210
%R 10.1021/acs.inorgchem.6b00926.s001
%2 https://ndownloader.figshare.com/files/5274796
%K UV
%K Cs 3 W 3 PO 13 crystallizes
%K space group Pnma
%K Cs 3 W 3 PO 13
%K tungsten phosphate
%K anisotropic
%X A new tungsten phosphate, Cs3W3PO13, is synthesized using the high-temperature
flux method. Cs3W3PO13 crystallizes
in the space group Pnma and contains one-dimensional
zigzag tunnels, which are found for the first time in tungsten phosphate.
This highly anisotropic structural feature results in a very strong
anisotropic thermal expansion, with thermal expansion coefficients
of 14.15 ± 1.11 and 0.72 ± 0.22 M K–1 along
the a and b axes, respectively,
over the temperature range from 13 to 270 K. In addition, thermal
analysis, UV–vis–near-IR diffuse reflectance, and first-principles
electronic structure calculations on Cs3W3PO13 are performed.
%I ACS Publications