%0 Generic %A Li, Zhaohui %A Zheng, Weiming %A Liu, Huang %A Mok, K. F. %A S. Andy Hor, T. %D 2003 %T Interpolymetallic Assembly of d8−d10 Sulfide Aggregates from [Pt2(PPh3)4(μ-S)2] and Group 12 Metals %U https://acs.figshare.com/articles/dataset/Interpolymetallic_Assembly_of_d_sup_8_sup_d_sup_10_sup_Sulfide_Aggregates_from_Pt_sub_2_sub_PPh_sub_3_sub_sub_4_sub_S_sub_2_sub_and_Group_12_Metals/3375868 %R 10.1021/ic034884+.s006 %2 https://ndownloader.figshare.com/files/5219341 %K S 2 CH 2 %K PPh 3 %K PF %K Group 12 Metals %K Pt 2 %K ZnPt 2 Cl 2 %K 10 Sulfide Aggregates %K CdPt 2 Cl 2 %X A series of heterometallic Pt−M (M = Zn and Cd) sulfide aggregates with growing nuclearities {Pt2M}, {Pt4M}, and {Pt4M2}, viz., [ZnPt2Cl2(PPh3)43-S)2] (2), [CdPt2Cl2(PPh3)43-S)2] (3), [Pt2(PPh3)43-S)2]2[ZnSO4]2 (4), [Pt2(PPh3)43-S)2]2[CdSO4]2·H2O (5), [CdPt4(PPh3)83-S)4][ClO4]2 (7), and [ZnPt4(PPh3)83-S)4][ClO4]2 (8), have been prepared from Pt2(PPh3)4(μ-S)2 (1) with appropriate zinc and cadmium substrates. The structures have been determined by single-crystal X-ray diffraction. The supporting anions play an active role in the structural assembly process. An unexpected disintegration complex [Pt2(S2CH2)Cl(PPh3)4][PF6] (6) has also been isolated and characterized by single-crystal X-ray diffraction. The mechanism of the formation of 6 is proposed. %I ACS Publications