Steric Control of Coordination Number: A Series of Mo(VI) Dioxo
Diaryloxide Complexes Bearing 4-, 5-, and 6-Coordinate Environments
Tracy A. Hanna
Amit K. Ghosh
Catalina Ibarra
Miguel A. Mendez-Rojas
Arnold L. Rheingold
William H. Watson
10.1021/ic035129z.s002
https://acs.figshare.com/articles/journal_contribution/Steric_Control_of_Coordination_Number_A_Series_of_Mo_VI_Dioxo_Diaryloxide_Complexes_Bearing_4_5_and_6_Coordinate_Environments/3349063
The design, synthesis, and structure determination of a series of Mo(VI) dioxo diaryloxide complexes have been
reported. By varying the steric bulk of the aryloxide ligand, control of the coordination number around the Mo(VI)
center was achieved. All the complexes are characterized by analytical and spectroscopic techniques. Preliminary
reactivity tests indicate that the 4-coordinate compound is the most stable and the 6-coordinate compound is the
least stable.
2004-02-23 00:00:00
spectroscopic techniques
Preliminary reactivity tests
coordination number
complex
aryloxide ligand
Mo
Steric Control
compound
steric bulk
structure determination