%0 Generic %A Spichal, Zdenek %A Necas, Marek %A Pinkas, Jiri %A Novosad, Josef %D 2004 %T The Synthesis and Crystal Structures of Two-Dimensional Coordination Polymers of Ph2P(O)−CH2CH2−P(O)Ph2 and Ph2P(O)−C5H3N−P(O)Ph2 with Praseodymium %U https://acs.figshare.com/articles/dataset/The_Synthesis_and_Crystal_Structures_of_Two_Dimensional_Coordination_Polymers_of_Ph_sub_2_sub_P_O_CH_sub_2_sub_CH_sub_2_sub_P_O_Ph_sub_2_sub_and_Ph_sub_2_sub_P_O_C_sub_5_sub_H_sub_3_sub_N_P_O_Ph_sub_2_sub_with_Praseodymium/3340939 %R 10.1021/ic0499648.s002 %2 https://ndownloader.figshare.com/files/5180152 %K building blocks %K lanthanide atoms %K square grid %K Ph %K Crystal Structures %K herringbone network %K Praseodymium Reactions %K CH %K praseodymium cations %K network coordination polymers %K bidentate ligands %X Reactions of Pr(NO3)3 with Ph2P(O)−CH2CH2−P(O)Ph2 and Ph2P(O)−C5H3N−P(O)Ph2 yielded layered network coordination polymers with bidentate ligands spanning the lanthanide atoms in a bridging fashion. The praseodymium cations with “spacer” ligands form two-dimensional building blocks assembling into either square grid or herringbone network. %I ACS Publications