Isolation and Characterization of a Carbene Derivative of La@C<sub>82</sub>
Yutaka Maeda
Yoichiro Matsunaga
Takatsugu Wakahara
Satomi Takahashi
Takahiro Tsuchiya
Midori O. Ishitsuka
Tadashi Hasegawa
Takeshi Akasaka
Michael T. H. Liu
Kisato Kokura
Ernst Horn
Kenji Yoza
Tatsuhisa Kato
Shingo Okubo
Kaoru Kobayashi
Shigeru Nagase
Kazunori Yamamoto
10.1021/ja0316115.s003
https://acs.figshare.com/articles/dataset/Isolation_and_Characterization_of_a_Carbene_Derivative_of_La_C_sub_82_sub_/3336400
The photochemical reaction of La@C<sub>82</sub> with 2-adamantane-2,3-[3H]-diazirine affords adduct <b>2</b>, La@C<sub>82</sub>(Ad), in a quantitative and highly selective manner. The structure of compound <b>2</b> is confirmed by ESR, MS, and UV−vis−NIR spectroscopies, and the first X-ray crystallographic characterization of an endohedral monometallofullerene derivative is reported.
2004-06-09 00:00:00
UV
La
compound 2
endohedral monometallofullerene
adduct 2
ESR
MS