%0 Journal Article
%A Ma, Bao-Qing
%A Sun, Hao-Ling
%A Gao, Song
%D 2005
%T Assembly of Hydrogen Bonded Diamondoid Networks Based on
Synthetic Metal-Organic Tetrahedral Nodes
%U https://acs.figshare.com/articles/journal_contribution/Assembly_of_Hydrogen_Bonded_Diamondoid_Networks_Based_on_Synthetic_Metal_Organic_Tetrahedral_Nodes/3300103
%R 10.1021/ic048648q.s003
%2 https://ndownloader.figshare.com/files/5137837
%K Synthetic
%K hydrogen bonds
%K species
%K tetrahedral moieties
%K metal centers
%K water molecules
%K H 2 O
%K assembly
%K Hydrogen Bonded Diamondoid Networks
%K Mn
%K octahedral environment
%K tetrahedral configuration
%K Co
%K 3 D diamondoid networks
%K dpdo ligands
%K Tetrahedral
%X Reaction of Mn(ClO4)2 or Co(PF6)2 with 4,4‘-dipyridine-dioxide
(dpdo) produced novel molecular species [M(dpdo)4(H2O)2]2+, which
hold a tetrahedral configuration notwithstanding their octahedral
environment around the metal centers. The tetrahedral moieties
are further assembled through hydrogen bonds between peripheral
NO ends of dpdo ligands and coordinated water molecules, giving
rise to 3D diamondoid networks.
%I ACS Publications