10.1021/ja055129t.s003
Chuanjiang Hu
Chuanjiang
Hu
Bruce C. Noll
Bruce C.
Noll
Charles E. Schulz
Charles E.
Schulz
W. Robert Scheidt
W. Robert
Scheidt
Proton-Mediated Electron Configuration Change in High-Spin Iron(II)
Porphyrinates
American Chemical Society
2005
structure characterization
M össbauer spectra
structure models
2005-11-02 00:00:00
Dataset
https://acs.figshare.com/articles/dataset/Proton_Mediated_Electron_Configuration_Change_in_High_Spin_Iron_II_Porphyrinates/3259597
The synthesis, molecular structure, and electronic structure characterization of two five-coordinate high-spin imidazolate-ligated iron(II) porphyrinates are reported. Their electronic structure, as deduced from Mössbauer spectra obtained in strong magnetic fields, is distinctly different from that of the analogous imidazole-ligated species. The resulting electronic structure models are consistent with all observed differing features in the two classes.