%0 Journal Article %A Ma, Ming %A Peng, Lingling %A Li, Changkun %A Zhang, Xiu %A Wang, Jianbo %D 2005 %T Highly Stereoselective [2,3]-Sigmatropic Rearrangement of Sulfur Ylide Generated through Cu(I) Carbene and Sulfides %U https://acs.figshare.com/articles/journal_contribution/Highly_Stereoselective_2_3_Sigmatropic_Rearrangement_of_Sulfur_Ylide_Generated_through_Cu_I_Carbene_and_Sulfides/3259591 %R 10.1021/ja055021d.s004 %2 https://ndownloader.figshare.com/files/5095003 %K sulfur ylide %K propargyl sulfides %K achiral diimine ligands %K chiral camphor sultam %K Sulfur Ylide Generated %K induction approach %K Cu %X A highly stereoselective [2,3]-sigmatropic rearrangement of sulfur ylide generated through Cu(I) carbene and allyl and propargyl sulfides by a double asymmetric induction approach that combines a chiral camphor sultam auxiliary and Cu(I) catalyst with chiral or achiral diimine ligands has been developed. %I ACS Publications