Ortiz-Marciales, Margarita Rivera, Luis D. Jesús, Melvin De Espinosa, Sandraliz Benjamin, Josúe A. Casanova, Orlando E. Figueroa, Irving G. Rodríguez, Sheila Correa, Wilbert Facile Rearrangement of <i>O</i>-Silylated Oximes on Reduction with Boron Trifluoride/Borane Aromatic <i>O</i>-triisopropylsilyl ketoximes were efficiently rearranged to cyclic and acyclic aniline derivatives on reduction with BF<sub>3</sub>-ethearate /borane. The bulk of the substituents on the silicon atom, the size of the aliphatic ring, and the presence of alkoxy substituents on the aryl group all play an important role in the aniline. borane;presence;aryl group;Aromatic;alkoxy substituents;triisopropylsilyl ketoximes;Facile Rearrangement;silicon atom;role;acyclic aniline derivatives;Boron;Trifluoride;bulk;BF 3;ethearate;Silylated Oximes;aliphatic ring 2005-11-25
    https://acs.figshare.com/articles/journal_contribution/Facile_Rearrangement_of_i_O_i_Silylated_Oximes_on_Reduction_with_Boron_Trifluoride_Borane/3255088
10.1021/jo0516178.s002