TY - DATA T1 - A Fluorobenzene Adduct of Ti(IV), and Catalytic Carboamination to Prepare α,β-Unsaturated Imines and Triaryl-Substituted Quinolines PY - 2005/12/28 AU - Falguni Basuli AU - Halikhedkar Aneetha AU - John C. Huffman AU - Daniel J. Mindiola UR - https://acs.figshare.com/articles/dataset/A_Fluorobenzene_Adduct_of_Ti_IV_and_Catalytic_Carboamination_to_Prepare_Unsaturated_Imines_and_Triaryl_Substituted_Quinolines/3249793 DO - 10.1021/ja0566026.s002 L4 - https://ndownloader.figshare.com/files/5084614 KW - CH KW - fluorobenzene adduct KW - latter product results KW - imine metathesis KW - nacnac KW - catalyzes carboamination reactions KW - Fluorobenzene Adduct KW - Catalytic Carboamination N2 - A rare fluorobenzene adduct of group 4, [(nacnac)TiNAr(FC6H5)][B(C6F5)4] (nacnac- = [ArNC(tBu)]2CH, Ar = 2,6-iPr2C6H3), has been isolated and structurally characterized. This highly electron-deficient system engages readily in imine metathesis and catalyzes carboamination reactions involving diphenylacetylene and aldimines to afford α,β-unsaturated imines as well as triaryl-substituted quinolines. The latter product results from cyclization of the corresponding electron-rich α,β-unsaturated imine. ER -