TY - DATA T1 - Novel Ambiphilic Dichlorocarbenoid Equivalent in Alkene Cyclopropanation and Carbonyl Olefination PY - 2006/05/26 AU - Ching-Ting Chien AU - Chia-Chung Tsai AU - Chi-Hui Tsai AU - Tsai-Yuan Chang AU - Ping-Kuei Tsai AU - Ying-Chuan Wang AU - Tu-Hsin Yan UR - https://acs.figshare.com/articles/journal_contribution/Novel_Ambiphilic_Dichlorocarbenoid_Equivalent_in_Alkene_Cyclopropanation_and_Carbonyl_Olefination/3220447 DO - 10.1021/jo052610t.s001 L4 - https://ndownloader.figshare.com/files/5054374 KW - Novel Ambiphilic Dichlorocarbenoid Equivalent KW - alkene cyclopropanations KW - CCl 4 KW - Ti KW - Alkene Cyclopropanation KW - Carbonyl Olefination KW - species KW - reactive KW - complex KW - carbonyl dichloromethylenations KW - Mg KW - novel class KW - bimetallic KW - ambiphilic dichlorocarbenoid equivalents KW - oxidative addition N2 - The Ti−Mg−dichloromethylene complexes derived from the oxidative addition of CCl4 to the Mg−TiCl4 bimetallic species serve as a novel class of ambiphilic dichlorocarbenoid equivalents. Not only is Ti−Mg−dichlorocarbenoid highly selective but also it seems highly reactive in both alkene cyclopropanations and carbonyl dichloromethylenations. ER -