10.1021/jo052610t.s001
Ching-Ting Chien
Ching-Ting
Chien
Chia-Chung Tsai
Chia-Chung
Tsai
Chi-Hui Tsai
Chi-Hui
Tsai
Tsai-Yuan Chang
Tsai-Yuan
Chang
Ping-Kuei Tsai
Ping-Kuei
Tsai
Ying-Chuan Wang
Ying-Chuan
Wang
Tu-Hsin Yan
Tu-Hsin
Yan
Novel Ambiphilic Dichlorocarbenoid Equivalent
in Alkene Cyclopropanation and Carbonyl
Olefination
American Chemical Society
2006
Novel Ambiphilic Dichlorocarbenoid Equivalent
alkene cyclopropanations
CCl 4
Ti
Alkene Cyclopropanation
Carbonyl Olefination
species
reactive
complex
carbonyl dichloromethylenations
Mg
novel class
bimetallic
ambiphilic dichlorocarbenoid equivalents
oxidative addition
2006-05-26 00:00:00
Journal contribution
https://acs.figshare.com/articles/journal_contribution/Novel_Ambiphilic_Dichlorocarbenoid_Equivalent_in_Alkene_Cyclopropanation_and_Carbonyl_Olefination/3220447
The Ti−Mg−dichloromethylene complexes derived from the
oxidative addition of CCl<sub>4</sub> to the Mg−TiCl<sub>4</sub> bimetallic
species serve as a novel class of ambiphilic dichlorocarbenoid
equivalents. Not only is Ti−Mg−dichlorocarbenoid highly
selective but also it seems highly reactive in both alkene
cyclopropanations and carbonyl dichloromethylenations.