Synthesis and Characterization of Imidocubanes with Exocube Ge<sup>IV</sup> and
Sn<sup>IV</sup> Substituents: [M(μ<sub>3</sub>-NGeMe<sub>3</sub>)]<sub>4</sub> (M = Sn, Ge, Pb); [Sn(μ<sub>3</sub>-NSnMe<sub>3</sub>)]<sub>4</sub>
Jack F. Eichler
Oliver Just
William S. Rees
10.1021/ic060331y.s006
https://acs.figshare.com/articles/dataset/Synthesis_and_Characterization_of_Imidocubanes_with_Exocube_Ge_sup_IV_sup_and_Sn_sup_IV_sup_Substituents_M_sub_3_sub_NGeMe_sub_3_sub_sub_4_sub_M_Sn_Ge_Pb_Sn_sub_3_sub_NSnMe_sub_3_sub_sub_4_sub_/3063844
The heteroleptic lithium amide, [(Me<sub>3</sub>Sn)(Me<sub>3</sub>Ge)NLi·(Et<sub>2</sub>O)]<sub>2</sub> (<b>2</b>), reacts with MCl<sub>2</sub> (M = Sn, Ge, Pb) to yield the
corresponding cubane complexes [M(μ<sub>3</sub>-NGeMe<sub>3</sub>)]<sub>4</sub> [M = Sn (<b>3</b>), Ge (<b>4</b>), Pb (<b>5</b>)]. In an analogous reaction with
SnCl<sub>2</sub>, the lithium stannylamide, [(Me<sub>3</sub>Sn)<sub>2</sub>NLi·(Et<sub>2</sub>O)]<sub>2</sub> (<b>1</b>), produces the mixed-valent Sn congener [Sn(μ<sub>3</sub>-NSnMe<sub>3</sub>)]<sub>4</sub>
(<b>6</b>). All imidocubanes contain both di- and tetravalent group 14 metals that are bridged by N. These structures are
comprised of M<sub>4</sub>N<sub>4</sub> (M = Sn, Pb, Ge) cores that possess varying distortion from perfect cube geometry. The Pb
derivative (<b>5</b>) exhibits enhanced volatility and vapor-phase integrity.
2006-08-21 00:00:00
cube geometry
Pb
MCl 2
M 4N
tetravalent group 14 metals
lithium stannylamide
Exocube GeIV
Sn
cubane complexes