TY - DATA T1 - Self-Assembling Poly(dioxaborole)s as Blue-Emissive Materials PY - 2006/12/27 AU - Weijun Niu AU - Mark D. Smith AU - John J. Lavigne UR - https://acs.figshare.com/articles/journal_contribution/Self_Assembling_Poly_dioxaborole_s_as_Blue_Emissive_Materials/3038113 DO - 10.1021/ja065986c.s001 L4 - https://ndownloader.figshare.com/files/4741525 KW - polymer KW - 60 000 KW - boronate ester formation KW - novel class KW - material N2 - Conjugated, borole-linked polymers have been self-assembled based on boronate ester formation between a fluorene-2,7-diboronic acid and 1,2,4,5-tetrahydroxybenzene. Readily soluble polymers with molecular weights approaching 60 000 have been generated with materials exhibiting extended conjugation over approximately 3−5 borole linkages. Emission from these polymers reaches into the visible (blue) range, representing a novel class of blue-emitting materials. ER -