datasetposted on 22.08.2005 by Ruifa Zong, Randolph P. Thummel
Datasets usually provide raw data for analysis. This raw data often comes in spreadsheet form, but can be any collection of data, on which analysis can be performed.
The title molecule, 2,2‘;9‘,2‘ ‘-ter[1,10]phenanthroline can be prepared from 2,9-dichloro-1,10-phenanthroline in three steps through the corresponding diacetyl intermediate. The ligand acts as a hexadentate with K+, while two molecules form a trinuclear, helical complex with Cu(I), which evidences π-stacking interactions and Cu−Cu distances of 3.01−3.04 Å. Electrochemical analysis shows a strong interaction between the Cu(I) centers.