Sila Morita−Baylis−Hillman Reaction of Cyclopropenes
Stepan Chuprakov
Denis A. Malyshev
Alexander Trofimov
Vladimir Gevorgyan
10.1021/ja077437s.s001
https://acs.figshare.com/articles/journal_contribution/Sila_Morita_Baylis_Hillman_Reaction_of_Cyclopropenes/2971135
The first example of sila-Morita-Bayis-Hillman reaction between 1-silylcyclopropenes and carbonyl compounds has been demonstrated. This novel phosphine-catalyzed transformation features a 1,3-Brook rearrangement/elimination cascade and provides convenient access to a variety of 1-(silyloxymethyl)cyclopropenes, which are not easily available via traditional methods.
2007-12-05 00:00:00
Brook
CyclopropenesThe
variety
access
Sila
rearrangement
silyloxymethyl
method
carbonyl compounds
silylcyclopropene
transformation
cascade
Morita