10.1021/cg800025y.s002
Guo-Ping Yong
Guo-Ping
Yong
Shu Qiao
Shu
Qiao
Zhi-Yong Wang
Zhi-Yong
Wang
A One-Dimensional Coordination Polymer Based on Novel Radical Anion Ligand Generated In Situ: Notable Magnetic and Luminescence Properties
American Chemical Society
2008
compound 1
aldol condensation
obip
ligand
Notable
species
hydrothermal reaction
hydrochloride salt
Hobip
anion coordination polymer
Novel Radical Anion Ligand Generated
deprotonation
emission
biimidazo
pyridin
imidazo
Luminescence Properties
Polymer
Zn
fluorescence
Coordination
ZnCl
antiferromagnetic
Situ
2008-05-07 00:00:00
Dataset
https://acs.figshare.com/articles/dataset/A_One_Dimensional_Coordination_Polymer_Based_on_Novel_Radical_Anion_Ligand_Generated_In_Situ_Notable_Magnetic_and_Luminescence_Properties/2940313
A one-dimensional Zn(II) radical anion coordination polymer, [ZnCl(obip<sup>•</sup>)]<i><sub>n</sub></i> (Hobip = 2,3′-biimidazo[1,2-<i>a</i>]pyridin-2′(3′<i>H</i>)-one) (<b>1</b>) was synthesized by a hydrothermal reaction between Zn(ClO<sub>4</sub>)<sub>2</sub>·6H<sub>2</sub>O and hydrochloride salt of imidazo[1,2-<i>a</i>]pyridin-2(3<i>H</i>)-one, in which the radical anion ligand ([obip]<sup>•−</sup>) was generated in situ by aldol condensation and then deprotonation. The compound <b>1</b> presents strong antiferromagnetic coupling between paramagnetic radical species and notable greenish yellow-red fluorescence emission.